One With Nature

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Precise Interception is a notable passive skill that grants increased attack damage, attack speed and additional chance to block attack damage with a shield equipped. It also grants increased armour rating, evasion rating, and energy shield from equipped shields.^[1]

Anointment

Blight anointment to unlock the passive:

Oil #1	Oil #2	Oil #3	Outcome
Verdant Oil	Crimson Oil	Black Oil	One With Nature	24% increased Elemental Damage with Attack Skills 24% increased Critical Strike Chance for Attacks +8% to all Elemental Resistances

Version	Changes
Unknown	Added 15% increased Physical Attack Damage while holding a Shield.
1.3.0	Reduced Chance to Block from 4% to 3% and increased Shield Defences from 30% to 60%. Block chance has been reduced, replaced, or removed throughout the tree.
0.11.2	Shield Wall has been renamed to Precise Interception and now offers 30% increased defences from your equipped Shield, instead of 20%.
0.11.0	Notable passives with non-unique names have been renamed to their own names.

↑ Mark_GGG (March 13, 2013). "Increased Shield Defenses?". Official Path of Exile Forums. Retrieved July 19, 2013.